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    Holiday Candy Canes

     Candy canes are a great treat, and during the holiday season, they are in abundance.  It gives us a chance to do a little experiment to learn about solubility. 

    Materials:

    • Candy canes (other hard candy)
    • Clear glasses
    • Cold water
    • Hot water
    • Oil (vegetable, corn, etc.)
    • Alka-Seltzer tablet
    • Measuring cup
        

    Safety:

    Always have an adult help you when using hot or boiling water.  The water and glasses can get very hot and may cause burns. Never taste or drink the mixtures – they’re for science only!

    Experiment:

    Line up four separate glasses and pour about a cup of the different liquids into each one (for the Alka-Seltzer tablet, use a cup of cold water and add the tablet).  Place a candy cane in each of the cups, and after 5 or 10 minutes (be consistent), remove the canes.  What happened to each one of the canes?

    photo of four candy canes in separate cups, each containing a different liquid, illiustrating different solubility of candy cane colors

    What’s happening?

    Candy canes are made out of sugar, which has the chemical formula shown below.  Notice all of the OH groups on the sugar.  

    atom-and-bond model of sucrose

    Water has the formula H2O, but it is arranged like H–O–H (lots of OH groups).  When looking at how much something dissolves in solution, we often say “like dissolves like”, which means that if two things are very similar, they will associate with each other.  Water starts associating with all of the OH groups in sugar and completely surrounds those sugar molecules – and dissolves the sugar.  By heating the water, the water molecules move faster and more quickly surrounds the sugar, and will dissolve the cane faster than the cold water.  The Alka-Seltzer fizz also causes the molecules to move around faster, giving a similar effect.  Oil has very little polarity and can be described as non-polar.  It lacks OH groups that would like to associate with the polar OH groups in water – so there is very little dissolving occurring. 

    Extension:

    What about other liquids such as ice water, soda, vinegar, vinegar with baking soda, salt water, sugar water, water with dishwashing soap?  Would dissolving (dissolution) occur faster if the candy cane were crushed?

    References:

    https://thehomeschoolscientist.com/dissolving-candy-canes-experiment/ 

    To view past “ChemShorts for Kids” activities, go to:
    https://chicagoacs.org/ChemShorts.

    - PAUL BRANDT